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Lemur [1.5K]
1 year ago
11

The initial concentrations of I2 and I− in the reaction below are each 0.0401 M. If the initial concentration of I−3 is 0.0 M an

d the equilibrium constant is Kc=0.25 under certain conditions, what is the equilibrium concentration (in molarity) of I−? I−3(aq)↽−−⇀I2(aq)+I−(aq)
Chemistry
1 answer:
lutik1710 [3]1 year ago
0 0

Answer:

[I⁻] = 0.0352M

Explanation:

Based on the equilibrium:

I₃⁻(aq) ⇄ I₂(aq) + I⁻(aq)

Kc is defined as:

Kc = 0.25 = [I₂] [I⁻] / [I₃⁻]

<em>The system reaches the equilbrium when the ratio</em> [I₂] [I⁻] / [I₃⁻] <em>is equal to 0.25</em>

In the beginning, you add 0.0401M of both [I₂] [I⁻].  When the reaction reach the equilibrium, xM of both [I₂] [I⁻] is consumed producing xM of  [I₃⁻]. That is written as:

[I₃⁻] = X

[I₂] = 0.0401M - X

[I⁻] = 0.0401M - X

<em>X is known as reaction coordinate.</em>

<em />

Replacing in Kc:

0.25 = [I₂] [I⁻] / [I₃⁻]

0.25 = [0.0401M - X] [0.0401M - X] / [X]

0.25X = 0.00160801 - 0.0802X + X²

0 = 0.00160801 - 0.3302X + X²

Solving for X:

X = 0.0049M → Right solution

X = 0.3252M → False solution. Produce negative concentrations

Replacing, equilibrium concentrations will be:

[I₃⁻] = X

[I₂] = 0.0401M - X

[I⁻] = 0.0401M - X

[I₃⁻] = 0.0049M

[I₂] = 0.0352M

<h3>[I⁻] = 0.0352M</h3>

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Answer:

a) 101%

b)59.7%

Explanation:

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2 moles of baking soda yields 1 mole of sodium carbonate

0.0185 moles of baking soda will yield = 0.0185 moles ×1 /2 = 9.25 ×10^-3 moles of sodium carbonate.

Therefore, mass of sodium carbonate= 9.25 ×10^-3 moles × 106gmol-1= 0.9805 g of sodium carbonate. This is the theoretical yield of sodium carbonate.

%yield = actual yield/theoretical yield ×100

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%yield = 101%

Since ;

2NaHCO3 → Na2CO3 + H2O + CO2

And H2O + CO2 ---> H2CO3

Hence I can write, 2NaHCO3 → Na2CO3 + H2CO3

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A bottle containing air is initially at a temperature of 33 degrees C and a pressure of 0.81 atm. After being placed in the free
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Answer:

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Explanation:

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Mathematically, Gay-Lussac's law states that, when a gas undergoes a constant volume transformation, the quotient of the pressure exerted by the gas temperature remains constant:

\frac{P}{T}  =k

When analyzing an initial state 1 and a final state 2, the following is satisfied:

\frac{P1}{T1}  =\frac{P2}{T2}

In this case:

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  • T1= 33 C= 306 K
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Replacing:

\frac{0.81 atm}{306 K}  =\frac{P2}{274 K}

Solving:

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P2= 0.725 atm

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